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Gibbs Energy Calculator.
Calculate Gibbs free-energy change from enthalpy, absolute temperature, and entropy change.
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Educational chemistry arithmetic only. Keep units consistent and verify assumptions against your laboratory or course specification.
Use Cases
Predict Reaction Spontaneity
Determine whether a chemical reaction is spontaneous under given conditions by calculating ΔG. Negative ΔG indicates a spontaneous process.
Example: For ΔH = -100 kJ/mol, T = 300 K, ΔS = 200 J/(mol·K), ΔG = -160 kJ/mol (spontaneous).
Evaluate Temperature Effects
Assess how changing temperature affects the spontaneity of a reaction, especially when ΔH and ΔS have opposite signs.
Example: For ΔH = +50 kJ/mol, ΔS = +100 J/(mol·K), reaction becomes spontaneous above 500 K.
Frequently Asked Questions
- What is Gibbs free energy and why is it important?
- Gibbs free energy (G) indicates the maximum reversible work a thermodynamic system can perform at constant temperature and pressure. Its change (ΔG) determines whether a reaction is spontaneous: negative ΔG means spontaneous, positive means non-spontaneous, and zero means equilibrium.
- How is Gibbs free energy change calculated?
- The calculator uses the equation ΔG = ΔH - TΔS, where ΔH is enthalpy change (J/mol), T is absolute temperature (K), and ΔS is entropy change (J/(mol·K)). Enter these values to get ΔG in J/mol.
- What units should I use for the inputs?
- Enter enthalpy change in J/mol, absolute temperature in Kelvin (K), and entropy change in J/(mol·K). The result will be in J/mol. Ensure temperature is in Kelvin, not Celsius, for correct calculations.
Tips & Common Mistakes
Tips
- Ensure temperature is in Kelvin (K). Convert from Celsius by adding 273.15.
- Double-check units: enthalpy in J/mol, entropy in J/(mol·K). If enthalpy is in kJ, convert to J by multiplying by 1000.
- Remember that ΔG depends on temperature; a reaction may be spontaneous at one temperature but not another.
- Use consistent units for all inputs to get the correct ΔG in J/mol.
Common Mistakes to Avoid
- Using Celsius instead of Kelvin for temperature, leading to incorrect ΔG values.
- Mixing units, e.g., entering enthalpy in kJ/mol while entropy is in J/(mol·K), without converting.
- Forgetting that ΔG = 0 at equilibrium; interpreting a zero result as non-spontaneous instead of equilibrium.
Last updated: August 13, 2026